Phosphorescent perylene imides

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Phosphorescent perylene imides.

Asymmetrically substituted perylene imide derivatives PIa and PIx display phosphorescence in glassy matrices at 77 K. The lifetime is 49.0 ms for PIa and 13.5 ms for PIx. The triplet energy is 1.79 eV for PIa and 1.68 eV for PIx as confirmed by sensitization experiments of the C(60) triplet.

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Removal of Nitric Oxide through Visible Light Photocatalysis by g‐C3N4 Modified with Perylene Imides

For photocatalytic removal of nitric oxide (NO), two major issues need to be addressed: incomplete oxidation of NO and deactivation of the photocatalyst. In this study, we aimed to solve these two problems by constructing an all-solid-state Z-scheme heterojunction (PI-g-C3N4) consisting of g-C3N4 surface modified with perylene imides (PI). PI-g-C3N4 exhibits significant enhancement in photocata...

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Two-channel photocatalytic production of H2O2 over g-C3N4 nanosheets modified with perylene imides

a Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics and Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011, People’s Republic of China University of Chinese Academy of Sciences, Beijing 100049, People’s Republic of China Nano Institute of Utah and Department of Materials Sci...

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Mechanochemical N-alkylation of imides

The mechanochemical N-alkylation of imide derivatives was studied. Reactions under solvent-free conditions in a ball mill gave good yields and could be put in place of the classical solution conditions. The method is general and can be applied to various imides and alkyl halides. Phthalimides prepared under ball milling conditions were used in a mechanochemical Gabriel synthesis of amines by th...

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Thermo-reversible gelation of rod-coil and coil-rod-coil molecules based on poly(dimethyl siloxane) and perylene imides and self-sorting of the homologous pair.

Organogels with perylene derivatives and phthalocyanines reported in the literature so far involve self-assembly promoted by hydrogen bonds, in addition to aromatic and van der Waals interactions. Although the self assembly of these types of molecules without a hydrogen bonding group in the structure occurs in solution or during crystallization, the gelation studies reported so far incorporated...

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ژورنال

عنوان ژورنال: Chemical Communications

سال: 2012

ISSN: 1359-7345,1364-548X

DOI: 10.1039/c2cc30948c